PLS-based EWMA fault detection strategy for process monitoring

Fault detection (FD) and diagnosis in industrial processes is essential to ensure process safety and maintain product quality. Partial least squares (PLS) has been used successfully in process monitoring because it can effectively deal with highly correlated process variables. However, the conventional PLS-based detection metrics, such as the Hotelling's T² and the Q statistics are ill suited to detect small faults because they only use information from the most recent observations. Other univariate statistical monitoring methods, such as the exponentially weighted moving average (EWMA) control scheme, has shown better abilities to detect small faults. However, EWMA can only be used to monitor single variables. Therefore, the main objective of this paper is to combine the advantages of the univariate EWMA and PLS methods to enhance their performances and widen their applicability in practice. The performance of the proposed PLS-based EWMA FD method was compared with that of the conventional PLS FD method through two simulated examples, one using synthetic data and the other using simulated distillation column data. The simulation results clearly show the effectiveness of the proposed method over the conventional PLS, especially in the presence of faults with small magnitudes.     

大肠杆菌吸附-化学还原法用废含金催化剂制备金纳米线

采用大肠杆菌吸附-化学还原法,以大肠杆菌(ECCs)为模板、十六烷基三甲基溴化铵为保护剂、抗坏血酸为还原剂,由废含金催化剂制备金纳米线(AuNWs)。采用XRD,SEM,TEM等技术对AuNWs进行表征。研究了AuNWs对罗丹明6G(R6G)和4-巯基苯甲酸(4-MBA)的拉曼散射信号的增强效果。实验结果表明:在制备过程中加入微生物ECCs,可使金回收率提高约20百分点;当溶液pH小于4时,反应2 h后,有大量呈线状的AuNWs聚集沉降,金回收率可达99%1以上。表征结果显示,AuNWs呈多晶结构,晶格间距为0.23 nm。表面增强拉曼散射分析表明,AuNWs对R6G和4-MBA具有良好的拉曼光谱增强性能。     

Research on flow assurance of deepwater submarine natural gas pipelines: Hydrate prediction and prevention

The formation of hydrate will lead to serious flow assurance problems in deepwater submarine natural gas transmission pipelines. However, the accurate evaluation model of the hydrate blocking risk for submarine natural gas transportation is still lacking. In this work, a novel model is established for evaluating the hydrate risk in deepwater submarine gas pipelines. Based on hydrate growth-deposition mechanism, the mathematical model mainly consists of mass, momentum and energy conservation equations. Meantime, the model results are obtained by finite difference method and iterative technique. Finally, the model has been applied in the production of deepwater gas field (L Gas Field) in China, and the sensitivity analysis of relevant parameters has been carried out. The results show that: (a). The mathematical model can well predict the hydrate blockage risk in deepwater natural gas pipelines after verification. (b). Hydrate is easily formed at the intersection of horizontal pipeline and vertical riser, and the maximum blocking position often occurs in middle of the riser. (c). The hydrate blockage degree and length of hydrate formation region (HFR) decrease with the increase of gas transport rate. (d). The hydrate blockage degree and length of HFR decrease with the increase of gas transport temperature. (e). The hydrate blockage degree and length of HFR increase with the extension of horizontal pipeline. (f). Injecting inhibitors can effectively inhibit hydrate formation and blockage, but the improvement of transmission measures can significantly reduce the dosage of inhibitor. It is concluded that measures such as increasing gas transportation rate and temperature, shortening horizontal pipeline length, optimizing inhibitor injection point and injection rate can play a safe, economic and efficient role in hydrate preventing and controlling.     

Safety assessment of the film boiling chemical vapor infiltration (FB-CVI) process through a system-theoretic accident model and process (STAMP)

Film boiling chemical vapor infiltration (FB-CVI) is considered as one of the fastest process methodologies for manufacturing carbon-carbon (C–C) composite products and possesses various advantages compared to conventional methodologies. However, there are safety concerns associated with this process for large-scale manufacturing, mainly owing to the intrinsic nature of the precursor and the process conditions. Considering the multifunctional interactions of the various systems during the process, a system-theoretic process analysis (STPA)/system theoretic accident model and process (STAMP) model is used to perform a safety analysis of the hazardous states of the FB-CVI process at the system level. As a case study, the FB-CVI process equipment employed for the manufacturing of C–C composites is considered. The safety constraints present in the system are assessed for adequacy through a hazard analysis by STPA/STAMP. The analysis through STPA/STAMP demonstrated the capability to create proactive strategies for the design and realization of process equipment that can be employed to manufacture C–C composite products through the FB-CVI process.     

Potential of microalgae as biopesticides to contribute to sustainable agriculture and environmental development

The loss of yields from agricultural production due to the presence of pests has been treated over the years with synthetic pesticides, but the use of these substances negatively affects the environment and presents health risks for consumers and animals. The development of agroecological systems using biopesticides represents a safe alternative that contributes to the reduction of agrochemical use and sustainable agriculture. Microalgae are able to biosynthesize a number of metabolites with potential biopesticidal action and can be considered potential biological agents for the control of harmful organisms to soils and plants. The present work aims to provide a critical perspective on the consequences of using synthetic pesticides, offering as an alternative the biopesticides obtained from microalgal biomass, which can be used together with the implementation of environmentally friendly agricultural systems.     

Review: recent advances in biogas purifying technologies

Biomethane production through biogas upgrading is a promising renewable energy for some industries which could be part of the equilibrium needed with fossil fuels consumption to achieve a sustainable society. This paper presents a comprehensive list of biogas upgrading technologies focused on carbon dioxide removal as well as recent advances reported by researcher with wide expertise in this topic. Additionally, an extensive costs–performance comparison among the technologies studied is discussed. Among the different alternatives, chemical scrubbing stood out to achieve high biomethane purities while cryogenic technologies proved to be effective against methane losses. Regarding the different costs, water scrubbing and membrane separation seem to be the most affordable techniques.     

活性炭吸附和两级Fenton氧化组合工艺处理高盐对氨基苯酚生产废水

采用活性炭吸附和两级Fenton氧化组合工艺对高盐度对氨基苯酚生产废水进行了处理实验研究。结果表明,p H值对活性炭去除有机物的影响较小。当活性炭投加量为4 g/L时,TOC去除率61%。分级加药可以有效提高Fenton氧化对有机物的去除效率。在温度为25℃、p H为3、30%H2O2投加量为3%(V/V)、Fe2+/H2O2摩尔比为0.05时,两级Fenton氧化处理后,出水TOC降至150 mg/L以下。此外,Fenton氧化后形成氢氧化铁污泥颗粒粒径为4.5μm,经过聚丙烯酰胺(PAM)絮凝之后,污泥的粒径明显增加,过滤特性改善。PAM絮凝效果依赖于溶液的p H值,当p H超过10后会失去作用,故在使用过程中需要严格控制溶液的p H值。     

A multi-path routing-inventory problem for a closed-loop supply chain considering the heterogeneous fleet of vehicles

In this paper, the inventory-routing problem is studied for a closed-loop supply chain. This closed-loop supply chain considers suppliers, manufacturers, whole-sellers, and disposal centers. To formulate this problem, a mixed integer linear programming model is proposed. This mathematical model minimizes the total costs of the supply chain, including the fixed and variable costs of vehicles, and holding inventory costs of final products and scraps. The proposed model considers the road roughness degree, multi-path setting and the heterogeneous fleet of vehicles, which increases its flexibility and the quality of solutions. Then, two symmetry-breaking constraints are proposed to reduce the complexity of the mathematical model. In order to evaluate the integrity of the proposed model, 20 instances of different sizes are randomly generated and solved. Finally, a comprehensive sensitivity analysis is conducted with respect to five key features of the problem, such as the impact of the symmetry-breaking constraints on the CPU time, multi-path setting, fixed cost of vehicles, heterogeneous fleet of vehicles, and lost sales. The results indicate that the consideration of multi-path setting and the heterogeneous fleet of vehicles improves the quality of solutions significantly.     

基于复杂系统建模的水管理政策研究进展

基于Agent的建模方法（ABSS）通过自下而上的方式，考察系统中主体的不同状态和行为特征、主体与环境的作用、主体之间的作用，来表征系统的宏观特征，是进行复杂社会环境系统分析和政策研究的重要手段，在水资源、水环境管理系统中得到了有效的应用。本文在大量文献调研的基础上，讨论了ABSS建模方法的基本原理、主要特征、系统构成、分类方法和开发工具等特征，总结了其供水系统发展、水资源分配和流域水资源管理、农业土地和水资源利用、居民用水行为、农业污染控制及人类活动的水环境影响等方面的应用，分析了其在研究内容、研究方法、研究结果等方面的发展趋势，讨论了利用该方法研究我国水资源管理和水污染控制政策的必要性和重要性。